HIDROLISIS LIGNOSELULOSA DAN KARAKTERISASI LIGNIN DARI MATERIAL LIMBAH KELAPA DENGAN METODE HIDROLISIS ASAM SULFAT

Cindy Yulia Febriani

Abstract


Penelitian ini melakukan hidrolisis lignoselulosa menggunakan asam sulfat dengan limbah kelapa berupa batok dan sabut kelapa untuk memeroleh zat lignin. Rasio padatan:larutan yang digunakan sebesar 3:25 (m/v). Variasi waktu pemanasan 2 hingga 5 jam. Lignin tidak larut asam yang diperoleh diuji karakterisasi menggunakan FT-IR dan SEM. Rata-rata yield lignin tidak larut dan larut asam pada batok kelapa lebih besar daripada sabut kelapa. Gugus metoksil menghilang setelah hidrolisis, gugus guaiasil terdeteksi pada batok kelapa setelah proses hidrolisis, adanya cincin aromatik yang berkaitan dengan lignin pada masing-masing sampel sebelum dan setelah hidrolisis, serta gugus siringil pada sabut kelapa sebelum dan setelah proses hidrolisis.

Keywords


batok; sabut; kelapa; lignin; hidrolisis; asam sulfat

Full Text:

PDF

References


Akpan, E., dan Adeosun, S. (2019), Sustainable Lignin for Carbon Fibers: Principles, Techniques, and Applications, Springer.

Beckham, G.T. (Ed.) (2018), Lignin Valorization: Emerging Approaches (Vol. 19), Royal Society of Chemistry.

Brauns, F., dan Brauns, D. (2013), The Chemistry of Lignin: Covering the Literature for the Years 1949 – 1958, Elsevier.

Calvo-Flores, F., dkk (2015), Lignin and lignans as renewable raw materials: chemistry, technology and applications, John Wiley & Sons.

Galiwango, E., dkk (2018), “Klason Method: An Effective Method for Isolation of Lignin Fractions from Date Palm Biomass Waste”, Chemical and Process Engineering Research, Res, 57, 46 – 58.

Ghaffar, S., dan Fan, M. (2013), Structural analysis for lignin characteristics in biomass straw, Biomass and Bioenergy, 57, 264 – 279.

Guo, M. (2013), Life cycle assessment (LCA) of light-weight eco-composites, Springer Science & Business Media.

Gupta, V., dan Tuohy, M. (2013), Biofuel Technologies: Recent Developments, Editorial Springer.

Gupta, V., dkk (2016), The Handbook of Microbial Bioresources, CABI.

Hon, D.-S., dan Shiraishi, N. (2000), Wood and Cellulosic Chemistry, Second Edition, Revised, and Expanded, CRC press.

Ishola, M. M., dkk (2015), “Simultaneous glucose and xylose utilization for improved ethanol production from lignocellulosic biomass through SSFF with encapsulated yeast”, Biomass and Bioenergy, 77(1), 192 – 199.

Kalia, S. (Ed.) (2017), Lignocellulosic Composite Materials, Springer.

Lin, S., dan Dence, C. (2012), Methods in Lignin Chemistry, Springer Science & Business Media.

Loow, Y. -L., dkk (2017). “Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion”, Cellulose, 24(9), 3591 – 3618.

Rajan, K., dan Carrier, D. J. (2014), “Effect of dilute acid pretreatment conditions and washing on the production of inhibitors and on recovery of sugars during wheat straw enzymatic hydrolysis”, Biomass and Bioenergy, 62(1), 222 – 227.

Raviv, M., dkk (Ed.) (2019), Soilless Culture: Theory and Practice: Theory and Practice, Elsevier.

Sluiter, A., dkk (2012), Determination of Structural Carbohydrates and Lignin in Biomass, National Renewable Energy Laboratory (NREL), Colorado.

TAPPI, T. (2002), 222 om-02: Acid-insoluble lignin in wood and pulp, 2002–2003 TAPPI Test Methods.

Thakur, V. K. (2014), Lignocellulosic Polymer Composites: Processing, Characterization, and Properties, John Wiley & Sons.

Váquez‐Torres, H., dkk (1992). “Coconut husk lignin. I. Extraction and characterization”. Journal of applied polymer science, 45(4), 633 – 644.

Yasuda, S., dkk (2001), “Formation and chemical structures of acid-soluble lignin I: sulfuric acid treatment time and acid-soluble lignin content of hardwood”, Journal of Wood Science, 47(1), 69 – 72.

Zabed, H., dkk (2017), “Bioethanol production from renewable sources: Current perspectives and technological progress”, Renewable and Sustainable Energy Reviews, 71(1), 475 – 501.




DOI: https://doi.org/10.29103/jtku.v10i2.5573

Article Metrics

 Abstract Views : 1094 times
 PDF Downloaded : 12 times

Refbacks

  • There are currently no refbacks.


Copyright (c) 2022 Cindy Yulia Febriani

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

E-ISSN:2580-5436
P-ISSN: 2303-3991

Creative Commons License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Flag Counter
View My Stats